JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001438
Submitter
The Noguchi Institute
Reaction ID
R-0000-001438
Regist Date
2012/06/21 17:02:39
REACTANT
MOLECULE ID
JCGG-COM0001697 (Reaction Tree)
MOLECULE ID
JCGG-COM0001698 (Reaction Tree)
Skeleton
JCGG-STR001188
MOLECULE ID
JCGG-COM0001699
Reactant Type
Ag2CO3
MOLECULE ID
JCGG-COM0000624
Reactant Type
AgOTf
PRODUCT
MOLECULE ID
JCGG-COM0001700 (Reaction Tree)
Yield
82%
REACTION DETAIL
Reaction Time
16 hours
Reaction Temp
-25 degree C
Solvent
CH2Cl2
Comment
Very few were described regarding this reaction.
Dry CaSO4 was included in the solvent.
COMMENT
Keywords: The synthesis of 1,2-cis-glycoside, alpha-glucopyranoside
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000093
Source
H. Paulsen and C. Kolar, Chem. Ber., 114, 306 (1981)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)