JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001436
Submitter
The Noguchi Institute
Reaction ID
R-0000-001436
Regist Date
2012/06/21 17:02:11
REACTANT
MOLECULE ID
JCGG-COM0001691 (Reaction Tree)
MOLECULE ID
JCGG-COM0001688 (Reaction Tree)
MOLECULE ID
JCGG-COM0001689
Reactant Type
HgBr2
PRODUCT
MOLECULE ID
JCGG-COM0001692 (Reaction Tree)
Product Type
alpha
Yield
75%(alpha/beta=19/81)
MOLECULE ID
JCGG-COM0001693 (Reaction Tree)
Skeleton
JCGG-STR001222
Product Type
beta
Yield
75%(alpha/beta=19/81)
REACTION DETAIL
Reaction Time
NOT specified
Reaction Temp
-20 degree C
Solvent
CH2Cl2
Comment
Very few were described regarding this reaction.
MS 4A was included in the solvent.
COMMENT
Keywords: The synthesis of 1,2-cis-glycoside, alpha-glucopyranoside
REFERENCE
Reference Id
REF-0000-000073
Source
第4版 実験化学講座 (26), 丸善
Reference Id
REF-0000-000074
Source
ISBN 4-621-03702-1
Reference Id
REF-0000-000091
Source
P.-H. A. Zollo, J.-C. Jacquinet, and P. Sinay, Carbohydr. Res., 122, 201 (1983)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)