|
Glycan Syntheses |
JCGG ID |
JCGG-RAC0001435 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001435
|
||||
Regist Date |
2012/06/21 17:02:01 | ||||
| REACTANT | |||||
|
|
|
||||
Reactant Type |
bromide | ||||
Mol |
7.47 mmol | ||||
|
|
|
||||
Mol |
7.49 mmol | ||||
|
|
|
||||
Reactant Type |
HgBr2 | ||||
Mol |
0.69 mmol | ||||
| PRODUCT | |||||
MOLECULE ID |
|
|
|||
Yield |
81% | ||||
| REACTION DETAIL | |||||
Reaction Time |
6 hours | ||||
Reaction Temp |
0 degree C | ||||
Solvent |
CH2Cl2 | ||||
Comment |
Bromide, HgBr2, and MS 4A were mixed and stirred for 60 minutes before the reaction. | ||||
| MS 4A was included in the solvent. | |||||
| COMMENT | |||||
| Keywords: The synthesis of 1,2-cis-glycoside, alpha-glucopyranoside | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000073 | ||||
Source |
第4版 実験化学講座 (26), 丸善 | ||||
Reference Id |
REF-0000-000074 | ||||
Source |
ISBN 4-621-03702-1 | ||||
Reference Id |
REF-0000-000091 | ||||
Source |
P.-H. A. Zollo, J.-C. Jacquinet, and P. Sinay, Carbohydr. Res., 122, 201 (1983) | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
|