Reaction:JCGG-RAC0001424

JCGG ID		JCGG-RAC0001424
Submitter		The Noguchi Institute
Reaction ID		R-0000-001424
Regist Date		2012/06/21 17:00:42
REACTANT
MOLECULE ID		JCGG-COM0001661 (Reaction Tree)
	Mol	1 mmol
MOLECULE ID		JCGG-COM0000606
	Reactant Type	DMF
	Volume	1.6 mL
MOLECULE ID		JCGG-COM0001662
	Reactant Type	(COBr)2 (1 M in CHCl3)
	Volume	3.1 mL
PRODUCT
MOLECULE ID		JCGG-COM0001663 (Reaction Tree)
	Yield	quantitative
REACTION DETAIL
Reaction Time		1.5 hours
Reaction Temp		5 to 10 degree C
Solvent		CHCl3
Comment		The addition of DMF was performed before the addition of (COBr)2.
		(COBr)2 was added dropwise.
COMMENT
Keywords: The synthesis methods of glycosyl donor, glycosyl halide
REFERENCE
Reference Id		REF-0000-000073
	Source	第4版実験化学講座 (26), 丸善
Reference Id		REF-0000-000074
	Source	ISBN 4-621-03702-1
Reference Id		REF-0000-000080
	Source	C. A. A. van Boeckel, T. Beetz, J. N. Vos, A. J. M. de Jong, S. F. van Aelst, R. H. van den Bosch, J. M. R. Mertens, and F. A. van der vlugt, J. Carbohydr. Chem., 4, 293 (1985)