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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001367 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001367
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Regist Date |
2012/06/21 16:54:24 | ||||
| REACTANT | |||||
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Reactant Type |
donor | ||||
Mol |
0.13 mmol | ||||
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Reactant Type |
acceptor | ||||
Mol |
0.10 mmol | ||||
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Reactant Type |
Cu(OTf)2 | ||||
Mol |
0.39 mmol | ||||
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Reactant Type |
Et3N | ||||
Volume |
0.5 mL | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
77% | ||||
| REACTION DETAIL | |||||
Reaction Time |
16 hours, 30 minutes | ||||
Reaction Temp |
40 degree C, NOT specified | ||||
Solvent |
ClCH2CH2Cl, ClCH2CH2Cl | ||||
Comment |
1) donor+acceptor, MS 4A, Cu(OTf)2, 2) +Et3N | ||||
| The donor, the acceptor, and MS 4A were mixed and stirred for 1 hour before the reaction. | |||||
| COMMENT | |||||
| Keywords: carbohydrates, glycosides, glycosylation, oligosaccharides, thioimidates | |||||
| There are multiple phases in this reaction. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000069 | ||||
Issn |
|||||
Doi |
10.1002/anie.200502694 | ||||
PubMed ID |
16224750 | ||||
Journal Name |
Angewandte Chemie (International ed. in English). (2005) 44 (43): 7123-6. | ||||
Article Title |
Development of an arming participating group for stereoselective glycosylation and chemoselective oligosaccharide synthesis. | ||||
Author |
James T, Smoot; Papapida, Pornsuriyasak; Alexei V, Demchenko | ||||
Affiliation |
Department of Chemistry and Biochemistry, University of Missouri-St. Louis, One University Boulevard, St. Louis, MO 63121, USA. | ||||
Reference Id |
REF-0000-000070 | ||||
Source |
Angew. Chem. Int. Ed. 2005, 44, 7123-7126 | ||||
Doi |
10.1002/anie.200502694 | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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