JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001361
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001361
Regist Date
 2012/06/21 16:53:44
REACTANT
MOLECULE ID
 JCGG-COM0001562 (Reaction Tree)
Skeleton
JCGG-STR002224
Mol
 0.093 mmol
MOLECULE ID
 JCGG-COM0001026
Reactant Type
 Pd (10% on charcoal)
Weight
 100 mg
MOLECULE ID
 JCGG-COM0000552
Reactant Type
 HCl (concentrated aq.)
Volume
 50 micro L
MOLECULE ID
 JCGG-COM0000414
Reactant Type
 H2 (gas)
PRODUCT
MOLECULE ID
 JCGG-COM0001563 (Reaction Tree)
Skeleton
JCGG-STR002224
Yield
 98%
REACTION DETAIL
Reaction Time
 4 hours
Reaction Temp
 room temp
Solvent
 EtOH/EtOAc = 1.5mL/1.5mL
COMMENT
Keywords: carbohydrates, glycosides, glycosylation, oligosaccharides, thioimidates
REFERENCE
Reference Id
 REF-0000-000069
Issn
 Print
Doi
 10.1002/anie.200502694
PubMed ID
 16224750
Journal Name
 Angewandte Chemie (International ed. in English). (2005) 44 (43): 7123-6.
Article Title
 Development of an arming participating group for stereoselective glycosylation and chemoselective oligosaccharide synthesis.
Author
 James T, Smoot; Papapida, Pornsuriyasak; Alexei V, Demchenko
Affiliation
 Department of Chemistry and Biochemistry, University of Missouri-St. Louis, One University Boulevard, St. Louis, MO 63121, USA.
Reference Id
 REF-0000-000070
Source
 Angew. Chem. Int. Ed. 2005, 44, 7123-7126
Doi
 10.1002/anie.200502694
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)