JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001357
Submitter
The Noguchi Institute
Reaction ID
R-0000-001357
Regist Date
2012/06/21 16:53:16
REACTANT
MOLECULE ID
JCGG-COM0001555 (Reaction Tree)
Mol
11.1 mmol
MOLECULE ID
JCGG-COM0000530
Reactant Type
NaOMe (0.1 M in MeOH)
Mol
1.11 mmol
PRODUCT
MOLECULE ID
JCGG-COM0001556 (Reaction Tree)
Yield
95%
REACTION DETAIL
Reaction Time
40 hours
Reaction Temp
room temp
Solvent
dry MeOH
COMMENT
Keywords: carbohydrates, glycosides, glycosylation, oligosaccharides, thioimidates
ATTENTION: There is a numerical discrepancy between the scheme and the written method. (the number of % yield)
REFERENCE
Reference Id
REF-0000-000069
Issn
Print
Doi
10.1002/anie.200502694
PubMed ID
16224750
Journal Name
Angewandte Chemie (International ed. in English). (2005) 44 (43): 7123-6.
Article Title
Development of an arming participating group for stereoselective glycosylation and chemoselective oligosaccharide synthesis.
Author
James T, Smoot; Papapida, Pornsuriyasak; Alexei V, Demchenko
Affiliation
Department of Chemistry and Biochemistry, University of Missouri-St. Louis, One University Boulevard, St. Louis, MO 63121, USA.
Reference Id
REF-0000-000070
Source
Angew. Chem. Int. Ed. 2005, 44, 7123-7126
Doi
10.1002/anie.200502694

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)