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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001347 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001348
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Regist Date |
2012/06/21 16:52:04 | ||||
| REACTANT | |||||
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Reactant Type |
acceptor | ||||
Mol |
14.9 micro mol | ||||
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Reactant Type |
donor | ||||
Mol |
37.1 micro mol | ||||
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Reactant Type |
NIS | ||||
Mol |
55.8 micro mol | ||||
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Reactant Type |
AgOTf | ||||
Mol |
5.84 micro mol | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
94% | ||||
| REACTION DETAIL | |||||
Reaction Time |
3 hours | ||||
Reaction Temp |
-40 degree C | ||||
Solvent |
dry CH2Cl2 | ||||
Comment |
Freshly dried MS3A was included in the solvent. | ||||
| The acceptor, the donor, and MS3A were mixed at room temperature before the reaction. | |||||
| COMMENT | |||||
| Keywords: stereoselective synthesis, mycobacterial arabinan, arabinofuranosyl donors, arabinofuranosylation, TIDPS | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000067 | ||||
Issn |
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Doi |
10.1021/ol062198j | ||||
PubMed ID |
17107063 | ||||
Journal Name |
Organic letters. (2006) 8 (24): 5525-8. | ||||
Article Title |
Stereoselective synthesis of a fragment of mycobacterial arabinan. | ||||
Author |
Akihiro, Ishiwata; Hiroko, Akao; Yukishige, Ito | ||||
Affiliation |
RIKEN (Institute of Physical and Chemical Research), Wako-shi, Saitama 351-0198, Japan. | ||||
Reference Id |
REF-0000-000068 | ||||
Source |
ORGANIC LETTERS, 2006, Vol. 8, No. 24, 5525-5528 | ||||
Doi |
10.1021/ol062198j | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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