JCGG ID |
JCGG-RAC0001329 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-001329 | |||||||
Regist Date |
2012/06/21 16:51:02 | |||||||
REACTANT | ||||||||
|
|
|||||||
Reactant Type |
donor | |||||||
Mol |
NOT specified | |||||||
|
|
|||||||
Reactant Type |
acceptor | |||||||
Mol |
1.0 equiv. | |||||||
|
|
|||||||
Reactant Type |
MeOTf | |||||||
Mol |
2.4 equiv. | |||||||
|
|
|||||||
Reactant Type |
DTBMP | |||||||
Mol |
2.4 equiv. | |||||||
PRODUCT | ||||||||
MOLECULE ID |
|
|
||||||
Product Type |
alpha | |||||||
Yield |
75%(alpha/beta=1/1.1) | |||||||
MOLECULE ID |
|
|
|
|||||
Product Type |
beta | |||||||
Yield |
75%(alpha/beta=1/1.1) | |||||||
REACTION DETAIL | ||||||||
Reaction Time |
1 hour | |||||||
Reaction Temp |
0 degree C | |||||||
Solvent |
xylene | |||||||
COMMENT | ||||||||
Keywords: stereoselective synthesis, mycobacterial arabinan, arabinofuranosyl donors, arabinofuranosylation, TIDPS | ||||||||
REFERENCE | ||||||||
Reference Id |
REF-0000-000067 | |||||||
Issn |
||||||||
Doi |
10.1021/ol062198j | |||||||
PubMed ID |
17107063 | |||||||
Journal Name |
Organic letters. (2006) 8 (24): 5525-8. | |||||||
Article Title |
Stereoselective synthesis of a fragment of mycobacterial arabinan. | |||||||
Author |
Akihiro, Ishiwata; Hiroko, Akao; Yukishige, Ito | |||||||
Affiliation |
RIKEN (Institute of Physical and Chemical Research), Wako-shi, Saitama 351-0198, Japan. | |||||||
Reference Id |
REF-0000-000068 | |||||||
Source |
ORGANIC LETTERS, 2006, Vol. 8, No. 24, 5525-5528 | |||||||
Doi |
10.1021/ol062198j |
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST) |