JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001313
Submitter
The Noguchi Institute
Reaction ID
R-0000-001313
Regist Date
2012/06/21 16:50:13
REACTANT
MOLECULE ID
JCGG-COM0001481 (Reaction Tree)
Mol
193 micro mol
MOLECULE ID
JCGG-COM0001344
Reactant Type
2,6-lutidine
Mol
1.23 mmol
MOLECULE ID
JCGG-COM0001483
Reactant Type
TIPSOTf
Mol
618 micro mol
PRODUCT
MOLECULE ID
JCGG-COM0001484 (Reaction Tree)
Yield
79%
REACTION DETAIL
Reaction Time
4 hours
Reaction Temp
90 degree C
Solvent
dry DMF
Comment
The reactants were mixed at room temperature before stirred at 90 degree in Celsius.
COMMENT
Keywords: stereoselective synthesis, mycobacterial arabinan, arabinofuranosyl donors, arabinofuranosylation, TIDPS
REFERENCE
Reference Id
REF-0000-000067
Issn
Print
Doi
10.1021/ol062198j
PubMed ID
17107063
Journal Name
Organic letters. (2006) 8 (24): 5525-8.
Article Title
Stereoselective synthesis of a fragment of mycobacterial arabinan.
Author
Akihiro, Ishiwata; Hiroko, Akao; Yukishige, Ito
Affiliation
RIKEN (Institute of Physical and Chemical Research), Wako-shi, Saitama 351-0198, Japan.
Reference Id
REF-0000-000068
Source
ORGANIC LETTERS, 2006, Vol. 8, No. 24, 5525-5528
Doi
10.1021/ol062198j

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