JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001306
Submitter
The Noguchi Institute
Reaction ID
R-0000-001306
Regist Date
2012/06/21 16:49:55
REACTANT
MOLECULE ID
JCGG-COM0001473 (Reaction Tree)
Mol
6.13 mmol
MOLECULE ID
JCGG-COM0000160
Reactant Type
NaH
Mol
18.4 mmol
MOLECULE ID
JCGG-COM0000161
Reactant Type
BnBr
Mol
13.5 mmol
PRODUCT
MOLECULE ID
JCGG-COM0001474 (Reaction Tree)
Yield
98%
REACTION DETAIL
Reaction Time
2 hours
Reaction Temp
room temp
Solvent
dry DMF
Comment
The reactants were mixed at 0 degree in Celsius before stirred at room temperature.
COMMENT
Keywords: stereoselective synthesis, mycobacterial arabinan, arabinofuranosyl donors, arabinofuranosylation, TIDPS
REFERENCE
Reference Id
REF-0000-000067
Issn
Print
Doi
10.1021/ol062198j
PubMed ID
17107063
Journal Name
Organic letters. (2006) 8 (24): 5525-8.
Article Title
Stereoselective synthesis of a fragment of mycobacterial arabinan.
Author
Akihiro, Ishiwata; Hiroko, Akao; Yukishige, Ito
Affiliation
RIKEN (Institute of Physical and Chemical Research), Wako-shi, Saitama 351-0198, Japan.
Reference Id
REF-0000-000068
Source
ORGANIC LETTERS, 2006, Vol. 8, No. 24, 5525-5528
Doi
10.1021/ol062198j

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)