JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001303
Submitter
The Noguchi Institute
Reaction ID
R-0000-001303
Regist Date
2012/06/21 16:49:47
REACTANT
MOLECULE ID
JCGG-COM0001469 (Reaction Tree)
Reactant Type
donor
Mol
0.264 mmol
MOLECULE ID
JCGG-COM0001468 (Reaction Tree)
Reactant Type
acceptor
Mol
0.131 mmol
MOLECULE ID
JCGG-COM0000009
Reactant Type
TMSOTf
Mol
0.028 mmol
PRODUCT
MOLECULE ID
JCGG-COM0001470 (Reaction Tree)
Yield
95%
REACTION DETAIL
Reaction Time
3 hours
Reaction Temp
-30 degree C
Solvent
Et2O
COMMENT
Keywords: beta-L-rhamnopyranosides, stereoselective synthesis, beta-D-mannopyranosides, intramolecular aglycon delivery, IAD
REFERENCE
Reference Id
REF-0000-000065
Issn
Electronic
Doi
10.1021/ja801574q
PubMed ID
18433121
Journal Name
Journal of the American Chemical Society. (2008) 130 (20): 6330-1.
Article Title
Stereoselective synthesis of beta-L-rhamnopyranosides.
Author
Yong Joo, Lee; Akihiro, Ishiwata; Yukishige, Ito
Affiliation
RIKEN (The Institute of Physical and Chemical Research), 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.
Reference Id
REF-0000-000066
Source
J. AM. CHEM. SOC. 2008, 130, 6330-6331
Doi
10.1021/ja801574q

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)