JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001302
Submitter
The Noguchi Institute
Reaction ID
R-0000-001302
Regist Date
2012/06/21 16:49:45
REACTANT
MOLECULE ID
JCGG-COM0001459 (Reaction Tree)
Reactant Type
naphthylidine acetal
Mol
0.066 mmol
MOLECULE ID
JCGG-COM0000667
Reactant Type
DIBAL-H (0.99 M)
Mol
0.129 mmol
PRODUCT
MOLECULE ID
JCGG-COM0001468 (Reaction Tree)
Yield
87%
REACTION DETAIL
Reaction Time
2 hours
Reaction Temp
room temp
Solvent
PhCH3
Comment
The reactants were mixed at 0 degree in Celsius before stirred at room temperature.
COMMENT
Keywords: beta-L-rhamnopyranosides, stereoselective synthesis, beta-D-mannopyranosides, intramolecular aglycon delivery, IAD
REFERENCE
Reference Id
REF-0000-000065
Issn
Electronic
Doi
10.1021/ja801574q
PubMed ID
18433121
Journal Name
Journal of the American Chemical Society. (2008) 130 (20): 6330-1.
Article Title
Stereoselective synthesis of beta-L-rhamnopyranosides.
Author
Yong Joo, Lee; Akihiro, Ishiwata; Yukishige, Ito
Affiliation
RIKEN (The Institute of Physical and Chemical Research), 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.
Reference Id
REF-0000-000066
Source
J. AM. CHEM. SOC. 2008, 130, 6330-6331
Doi
10.1021/ja801574q

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)