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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001296 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001296
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Regist Date |
2012/06/21 16:49:25 | ||||
| REACTANT | |||||
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Reactant Type |
acetal | ||||
Mol |
1 equiv. | ||||
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Reactant Type |
DTBMP | ||||
Mol |
4 equiv. | ||||
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Reactant Type |
MeOTf | ||||
Mol |
3.5 equiv. | ||||
| PRODUCT | |||||
MOLECULE ID |
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Product Type |
beta | ||||
Yield |
83%(beta only) | ||||
| REACTION DETAIL | |||||
Reaction Time |
48 hours | ||||
Reaction Temp |
room temp | ||||
Solvent |
(CH2Cl)2 | ||||
Comment |
MS 4A was included in the solvent. | ||||
| COMMENT | |||||
| Keywords: beta-L-rhamnopyranosides, stereoselective synthesis, beta-D-mannopyranosides, intramolecular aglycon delivery, IAD | |||||
| The alpha/beta ratio was determined by 1H NMR after isolation. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000065 | ||||
Issn |
Electronic | ||||
Doi |
10.1021/ja801574q | ||||
PubMed ID |
18433121 | ||||
Journal Name |
Journal of the American Chemical Society. (2008) 130 (20): 6330-1. | ||||
Article Title |
Stereoselective synthesis of beta-L-rhamnopyranosides. | ||||
Author |
Yong Joo, Lee; Akihiro, Ishiwata; Yukishige, Ito | ||||
Affiliation |
RIKEN (The Institute of Physical and Chemical Research), 2-1 Hirosawa, Wako, Saitama 351-0198, Japan. | ||||
Reference Id |
REF-0000-000066 | ||||
Source |
J. AM. CHEM. SOC. 2008, 130, 6330-6331 | ||||
Doi |
10.1021/ja801574q | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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