JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001293
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001293
Regist Date
 2012/06/21 16:49:13
REACTANT
MOLECULE ID
 JCGG-COM0001453 (Reaction Tree)
Reactant Type
 donor
Mol
 0.221 mmol
MOLECULE ID
 JCGG-COM0000071 (Reaction Tree)
Skeleton
JCGG-STR032525
Reactant Type
 acceptor
Mol
 0.18 mmol
MOLECULE ID
 JCGG-COM0000743
Reactant Type
 DDQ
Mol
 0.22 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0001456 (Reaction Tree)
Yield
 93%
REACTION DETAIL
Reaction Time
 4 hours
Reaction Temp
 0 degree C
Solvent
 CH2Cl2
Comment
 MS 4A was included in the solvent.
COMMENT
Keywords: beta-L-rhamnopyranosides, stereoselective synthesis, beta-D-mannopyranosides, intramolecular aglycon delivery, IAD
REFERENCE
Reference Id
 REF-0000-000065
Issn
 Electronic
Doi
 10.1021/ja801574q
PubMed ID
 18433121
Journal Name
 Journal of the American Chemical Society. (2008) 130 (20): 6330-1.
Article Title
 Stereoselective synthesis of beta-L-rhamnopyranosides.
Author
 Yong Joo, Lee; Akihiro, Ishiwata; Yukishige, Ito
Affiliation
 RIKEN (The Institute of Physical and Chemical Research), 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.
Reference Id
 REF-0000-000066
Source
 J. AM. CHEM. SOC. 2008, 130, 6330-6331
Doi
 10.1021/ja801574q
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)