Reaction:JCGG-RAC0001272

JCGG ID		JCGG-RAC0001272
Submitter		The Noguchi Institute
Reaction ID		R-0000-001272
Regist Date		2012/06/21 16:48:15
REACTANT
MOLECULE ID		JCGG-COM0001370
	Mol	0.66 mmol
MOLECULE ID		JCGG-COM0001418 (Reaction Tree)
	Mol	0.65 mmol
MOLECULE ID		JCGG-COM0001377
	Reactant Type	KOtBu (1 M in THF)
	Volume	0.52 (NO unit specified)
PRODUCT
MOLECULE ID		JCGG-COM0001428 (Reaction Tree)
	Yield	70%
REACTION DETAIL
Reaction Time		10 minutes + 3 hours
Reaction Temp		room temp
Solvent		dry PhCH3
Comment		37 was added 10 minutes after the start of the reaction.
COMMENT
Keywords: galactal derivatives, 6-O-TIPS protection, trichloroacetimidates, Michael-type addition, 2-nitroglycals
REFERENCE
Reference Id		REF-0000-000063
	Issn	Print
	Doi	10.1021/jo061670b
	PubMed ID	17503844
	Journal Name	The Journal of organic chemistry. (2007) 72 (12): 4367-77.
	Article Title	Glycal glycosylation and 2-nitroglycal concatenation, a powerful combination for mucin core structure synthesis.
	Author	Jürgen, Geiger; B Gopal, Reddy; Gottfried A, Winterfeld; R, Weber; M, Przybylski; R R, Schmidt
	Affiliation	Fachbereich Chemie, Universität Konstanz, Fach M 725, D - 78457 Konstanz, Germany.
Reference Id		REF-0000-000064
	Source	J. Org. Chem. 2007, 72, 4367-4377
	Doi	10.1021/jo061670b