|
Glycan Syntheses |
JCGG ID |
JCGG-RAC0001122 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001122
|
||||
Regist Date |
2012/06/21 16:40:16 | ||||
| REACTANT | |||||
|
|
|
||||
Reactant Type |
glycal | ||||
Mol |
1 equiv. | ||||
|
|
|
||||
Reactant Type |
NaOH (1% in MeOH) | ||||
Volume |
1 mL | ||||
|
|
|
||||
Reactant Type |
imidazole | ||||
Mol |
5 equiv. | ||||
|
|
|
||||
Reactant Type |
TBDMSCl | ||||
Mol |
2.5 equiv. | ||||
| PRODUCT | |||||
MOLECULE ID |
|
|
|||
Yield |
78%(99%, 79%) | ||||
| REACTION DETAIL | |||||
Reaction Time |
1 hour, 15 hours | ||||
Reaction Temp |
room temp, NOT specified | ||||
Solvent |
MeOH/ether = 10/1, DMF | ||||
Comment |
1) 17+NaOH, 2) +all the rest | ||||
| COMMENT | |||||
| The PMID could not be found. | |||||
| There are two phases in this reaction. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000051 | ||||
Source |
J. Am. Chem. Soc., 1989, 111 (17), pp 6656-6660 | ||||
Doi |
10.1021/ja00199a027 | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
|