JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001119
Submitter
The Noguchi Institute
Reaction ID
R-0000-001119
Regist Date
2012/06/21 16:40:07
REACTANT
MOLECULE ID
JCGG-COM0001244 (Reaction Tree)
Reactant Type
glycal
Mol
1 equiv.
MOLECULE ID
JCGG-COM0000418
Reactant Type
NaOH (1% in MeOH)
Volume
1 mL
MOLECULE ID
JCGG-COM0000759
Reactant Type
imidazole
Mol
5 equiv.
MOLECULE ID
JCGG-COM0000501
Reactant Type
TBDMSCl
Mol
2.5 equiv.
PRODUCT
MOLECULE ID
JCGG-COM0001254 (Reaction Tree)
Yield
77%(86%, 90%)
REACTION DETAIL
Reaction Time
1 hour, 15 hours
Reaction Temp
room temp, NOT specified
Solvent
MeOH/ether = 10/1, DMF
Comment
1) 13+NaOH, 2) +all the rest
COMMENT
The PMID could not be found.
There are two phases in this reaction.
REFERENCE
Reference Id
REF-0000-000051
Source
J. Am. Chem. Soc., 1989, 111 (17), pp 6656-6660
Doi
10.1021/ja00199a027

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)