|
Glycan Syntheses |
JCGG ID |
JCGG-RAC0001096 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-001103
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Regist Date |
2012/06/21 16:39:19 | |||||||
| REACTANT | ||||||||
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Reactant Type |
1-Hydroxy sugar | |||||||
Mol |
1 equiv. | |||||||
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|||||||
Reactant Type |
ROH | |||||||
Mol |
1 equiv. | |||||||
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Reactant Type |
Bi(OTf)3 | |||||||
Mol |
0.05 equiv. | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
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Product Type |
alpha | |||||||
Yield |
87%(alpha/beta=69/31) | |||||||
MOLECULE ID |
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Product Type |
beta | |||||||
Yield |
87%(alpha/beta=69/31) | |||||||
MOLECULE ID |
|
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||||||
Product Type |
by-product | |||||||
Yield |
9% | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
15 minutes | |||||||
Reaction Temp |
reflux | |||||||
Solvent |
CH2Cl2 | |||||||
Comment |
anhydrous CaSO4 was included in the solvent. | |||||||
| COMMENT | ||||||||
| The PMID could not be found. | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000050 | |||||||
Source |
Letters in Organic Chemistry, 2008, 5, 30-33 | |||||||
Doi |
10.1002/chin.200820195 | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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