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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001029 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001031
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Regist Date |
2012/06/21 16:35:44 | ||||
| REACTANT | |||||
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Mol |
0.00344 mmol (1 equiv.) | ||||
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Reactant Type |
hydrazine hydrate | ||||
Volume |
2 mL | ||||
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Reactant Type |
PamCysSer | ||||
Mol |
3.0 equiv. | ||||
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Reactant Type |
Hunig's base (DIEA) | ||||
Volume |
1 drop (excess) | ||||
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Reactant Type |
HATU | ||||
Mol |
2 equiv. | ||||
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Reactant Type |
HOAT | ||||
Mol |
4 equiv. | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
21%(first/second=70%/30%) | ||||
| REACTION DETAIL | |||||
Reaction Time |
4 days , 20 hours | ||||
Reaction Temp |
room temp, NOT specified | ||||
Solvent |
MeOH (8 mL), DMF (1 mL) | ||||
Comment |
1) 27+hydrazine hydrate, 2) +all the rest | ||||
| COMMENT | |||||
| The PMID could not be found. | |||||
| There are two phases in this reaction. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000046 | ||||
Source |
J. Am. Chem. Soc. 2000, 122, 7273-7279 | ||||
Doi |
10.1021/ja0011820 | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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