JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000996
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000997
Regist Date
 2012/06/21 16:33:43
REACTANT
MOLECULE ID
 JCGG-COM0001019 (Reaction Tree)
Skeleton
JCGG-STR025660
Mol
 0.521 mmol
MOLECULE ID
 JCGG-COM0001121 (Reaction Tree)
Mol
 0.104 mmol
MOLECULE ID
 JCGG-COM0000129
Reactant Type
 NIS
Mol
 1.30 mmol
MOLECULE ID
 JCGG-COM0000111
Reactant Type
 TfOH (1% in CH2Cl2)
Mol
 0.521 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0001122 (Reaction Tree)
Yield
 69%
REACTION DETAIL
Reaction Time
 30 minutes, 12 hours
Reaction Temp
 room temp, room temp
Solvent
 CH2Cl2, CH2Cl2
Comment
 1) 23+19, MS 4A, 2) +all the rest
MS 4A was included in the solvent.
The reactants were mixed at 0 degree in Celsius, and allowed to raise to room temperature within the reaction time. (second phase)
COMMENT
The PMID could not be found.
There are two phases in this reaction.
REFERENCE
Reference Id
 REF-0000-000046
Source
 J. Am. Chem. Soc. 2000, 122, 7273-7279
Doi
 10.1021/ja0011820
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)