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Glycan Syntheses |
JCGG ID |
JCGG-RAC0000986 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-000987
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Regist Date |
2012/06/21 16:33:14 | ||||
| REACTANT | |||||
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Mol |
25.1 mmol | ||||
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Reactant Type |
A | ||||
Mol |
30.1 mmol | ||||
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Reactant Type |
TMSOTf (1% in CH2Cl2) | ||||
Volume |
91 micro L | ||||
| PRODUCT | |||||
MOLECULE ID |
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Product Type |
alpha | ||||
Yield |
75%(alpha/beta=1/1.7) | ||||
MOLECULE ID |
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Product Type |
beta | ||||
Yield |
75%(alpha/beta=1/1.7) | ||||
| REACTION DETAIL | |||||
Reaction Time |
2 hours | ||||
Reaction Temp |
-10 degree C | ||||
Solvent |
CH2Cl2 | ||||
Comment |
MS 4A was included in the solvent. | ||||
| The reactants were mixed at -40 degree in Celsius, and raised to -10 degree within the reaction time. | |||||
| COMMENT | |||||
| The PMID could not be found. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000046 | ||||
Source |
J. Am. Chem. Soc. 2000, 122, 7273-7279 | ||||
Doi |
10.1021/ja0011820 | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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