JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000948
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000948
Regist Date
 2012/06/21 16:31:20
REACTANT
MOLECULE ID
 JCGG-COM0001074 (Reaction Tree)
Skeleton
JCGG-STR025422
Mol
 0.0328 mmol
MOLECULE ID
 JCGG-COM0001065
Reactant Type
 PivCl
Mol
 0.197 mmol
MOLECULE ID
 JCGG-COM0001066
Reactant Type
 AcHNCH2CH2OH
Mol
 0.109 mmol
MOLECULE ID
 JCGG-COM0000084
Reactant Type
 I2
Mol
 0.036 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0001075 (Reaction Tree)
Yield
 58%
REACTION DETAIL
Reaction Time
 20 minutes + 2 hours, overnight
Reaction Temp
 -20 degree C, room temp
Solvent
 pyridine, pyridine
Comment
 1) 16+PivCl, AcHNCH2CH2OH, 2) +I2
PivCl was added dropwise for 20 minutes
COMMENT
The PMID could not be found.
There are two phases in this reaction.
ATTENTION: There are typos in the written method. (compound 6 should be 16, compound 2 should be 17)
REFERENCE
Reference Id
 REF-0000-000043
Source
 HETEROCYCLES, Vol. 52, No. 2, 2000, pp. 921-928
Doi
 10.3987/COM-99-S65
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