JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000920
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000911
Regist Date
 2012/06/21 16:29:40
REACTANT
MOLECULE ID
 JCGG-COM0001038 (Reaction Tree)
Reactant Type
 Ac-[Ser(O-hexa saccharide)]3-AlaValAlaVal-OBn
Weight
 24.0mg
MOLECULE ID
 JCGG-COM0001026
Reactant Type
 Pd-C (5%)
Mol
 catalytic amount
MOLECULE ID
 JCGG-COM0000414
Reactant Type
 H2 (gas)
MOLECULE ID
 JCGG-COM0000057
Reactant Type
 MeOH (solvent)
Volume
 8 mL
MOLECULE ID
 JCGG-COM0000489
Reactant Type
 hydrazine hydrate (solvent)
Volume
 2 mL
PRODUCT
MOLECULE ID
 JCGG-COM0001039 (Reaction Tree)
Yield
 70%
REACTION DETAIL
Reaction Time
 30 minutes, 4 days
Reaction Temp
 NOT specified, room temp
Solvent
 MeOH/H2O = 15/1, MeOH/hydrazine hydrate = 8mL/2mL
Comment
 1) Ac-[Ser(O-hexa saccharide)]3-AlaValAlaVal-OBn+Pd-C, H2, 2) +all the rest
The reaction temperature could not be found. (considered to be room temp; first phase)
COMMENT
The PMID could not be found.
There are two phases in this reaction.
REFERENCE
Reference Id
 REF-0000-000041
Source
 J. Am. Chem. Soc. 1999, 121, 10636-10637
Doi
 10.1021/ja992309s
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)