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Glycan Syntheses |
JCGG ID |
JCGG-RAC0000902 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-000902
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Regist Date |
2012/06/21 16:29:07 | ||||
| REACTANT | |||||
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Reactant Type |
TBS-ether | ||||
Mol |
0.0931 mmol | ||||
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Reactant Type |
AcOH | ||||
Mol |
5.59 mmol | ||||
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Reactant Type |
TBAF (1 M in THF) | ||||
Mol |
1.40 mmol | ||||
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Reactant Type |
Ac2O (solvent) | ||||
Volume |
2 mL | ||||
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Reactant Type |
pyridine (solvent) | ||||
Volume |
1 mL | ||||
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Reactant Type |
DMAP | ||||
Mol |
catalytic amount | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
96% | ||||
| REACTION DETAIL | |||||
Reaction Time |
20 hours, 2 hours | ||||
Reaction Temp |
room temp, room temp | ||||
Solvent |
THF, Ac2O/pyridine = 2mL/1mL | ||||
Comment |
1) TBS-ester+AcOH, TBAF, 2) +all the rest | ||||
| COMMENT | |||||
| The PMID could not be found. | |||||
| There are two phases in this reaction. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000041 | ||||
Source |
J. Am. Chem. Soc. 1999, 121, 10636-10637 | ||||
Doi |
10.1021/ja992309s | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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