Reaction:JCGG-RAC0000881

JCGG ID		JCGG-RAC0000881
Submitter		The Noguchi Institute
Reaction ID		R-0000-000881
Regist Date		2012/06/21 16:28:05
REACTANT
MOLECULE ID		JCGG-COM0000332 (Reaction Tree)
	Reactant Type	1-C-Vinyl-glycopyranose derivative
	Mol	1 equiv.
MOLECULE ID		JCGG-COM0000009
	Reactant Type	TMSOTf
	Mol	0.2 equiv.
MOLECULE ID		JCGG-COM0000219
	Reactant Type	Nucleophile
	Mol	3 equiv.
PRODUCT
MOLECULE ID		JCGG-COM0000333 (Reaction Tree)
	Product Type	Z
	Yield	94%(Z/E=91/9)
MOLECULE ID		JCGG-COM0001007 (Reaction Tree)
	Product Type	E
	Yield	94%(Z/E=91/9)
REACTION DETAIL
Reaction Time		2 hours
Reaction Temp		-78 degree C
Solvent		MeCN/CH2Cl2 = 1/1
Comment		Dry CaSO4 was included in the solvent.
COMMENT
The PMID could not be found.
REFERENCE
Reference Id		REF-0000-000039
	Source	SYNLETT 2007, No. 5, pp 0785-0789
	Doi	10.1055/s-2007-970751