JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000878
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000878
Regist Date
 2012/06/21 16:27:56
REACTANT
MOLECULE ID
 JCGG-COM0000278 (Reaction Tree)
Reactant Type
 1-C-Vinyl-glycopyranose derivative
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000286
Reactant Type
 Nucleophile
Mol
 3 equiv.
MOLECULE ID
 JCGG-COM0000009
Reactant Type
 TMSOTf
Mol
 0.2 equiv.
PRODUCT
MOLECULE ID
 JCGG-COM0000287 (Reaction Tree)
Yield
 74%
REACTION DETAIL
Reaction Time
 2 hours
Reaction Temp
 -78 degree C
Solvent
 MeCN/CH2Cl2 = 1/1
Comment
 Dry CaSO4 was included in the solvent.
COMMENT
The PMID could not be found.
REFERENCE
Reference Id
 REF-0000-000039
Source
 SYNLETT 2007, No. 5, pp 0785-0789
Doi
 10.1055/s-2007-970751
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)