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Glycan Syntheses |
JCGG ID |
JCGG-RAC0000759 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-000763
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Regist Date |
2012/06/21 16:22:23 | ||||
| REACTANT | |||||
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Mol |
0.0118 mmol | ||||
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Reactant Type |
NaOMe (28% in MeOH) | ||||
Mol |
catalytic amounts | ||||
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Reactant Type |
KOH (0.2 M) | ||||
Volume |
0.2 mL | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
83% (at least) | ||||
| REACTION DETAIL | |||||
Reaction Time |
12 hours, 24 hours, 3 hours | ||||
Reaction Temp |
room temp, 50 degree C, room temp | ||||
Solvent |
MeOH, MeOH, MeOH | ||||
Comment |
1) 43+NaOMe, 2) temperature change, 3) +KOH | ||||
| COMMENT | |||||
| There are three phases in this reaction. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000035 | ||||
Issn |
Electronic | ||||
Doi |
10.1021/jo8027888 | ||||
PubMed ID |
19296672 | ||||
Journal Name |
The Journal of organic chemistry. (2009) 74 (8): 3009-23. | ||||
Article Title |
Ganglioside GQ1b: efficient total synthesis and the expansion to synthetic derivatives to elucidate its biological roles. | ||||
Author |
Akihiro, Imamura; Hiromune, Ando; Hideharu, Ishida; Makoto, Kiso | ||||
Affiliation |
Department of Applied Bioorganic Chemistry, Faculty of Applied Biological Sciences, Gifu University, 1-1 Yanagido, Gifu-shi, Gifu 501-1193, Japan. aimamura@ualberta.ca | ||||
Reference Id |
REF-0000-000036 | ||||
Source |
J. Org. Chem. 2009, 74, 3009-3023 | ||||
Doi |
10.1021/jo8027888 | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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