JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000754
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000754
Regist Date
 2012/06/21 16:21:55
REACTANT
MOLECULE ID
 JCGG-COM0000846 (Reaction Tree)
Skeleton
JCGG-STR031569
Mol
 0.0758 mmol
MOLECULE ID
 JCGG-COM0000847
Reactant Type
 DABCO
Mol
 1.13 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0000848 (Reaction Tree)
Skeleton
JCGG-STR031569
Yield
 96%
REACTION DETAIL
Reaction Time
 5 hours
Reaction Temp
 55 degree C
Solvent
 EtOH/(CH2Cl)2 = 3.6mL/1.2mL
Comment
 The reactants were mixed at room temperature before stirred at 55 degree in Celsius.
COMMENT
REFERENCE
Reference Id
 REF-0000-000035
Issn
 Electronic
Doi
 10.1021/jo8027888
PubMed ID
 19296672
Journal Name
 The Journal of organic chemistry. (2009) 74 (8): 3009-23.
Article Title
 Ganglioside GQ1b: efficient total synthesis and the expansion to synthetic derivatives to elucidate its biological roles.
Author
 Akihiro, Imamura; Hiromune, Ando; Hideharu, Ishida; Makoto, Kiso
Affiliation
 Department of Applied Bioorganic Chemistry, Faculty of Applied Biological Sciences, Gifu University, 1-1 Yanagido, Gifu-shi, Gifu 501-1193, Japan. aimamura@ualberta.ca
Reference Id
 REF-0000-000036
Source
 J. Org. Chem. 2009, 74, 3009-3023
Doi
 10.1021/jo8027888
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)