JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0000713
Submitter
The Noguchi Institute
Reaction ID
R-0000-000713
Regist Date
2012/06/21 16:19:50
REACTANT
MOLECULE ID
JCGG-COM0000085 (Reaction Tree)
Reactant Type
1-C-Methylated donor
Mol
1 equiv.
MOLECULE ID
JCGG-COM0000054 (Reaction Tree)
Reactant Type
Aldopyranose of acceptor
Mol
0.67 equiv.
MOLECULE ID
JCGG-COM0000113
Reactant Type
Activator
Mol
0.05 equiv.
PRODUCT
MOLECULE ID
JCGG-COM0000346 (Reaction Tree)
Product Type
alpha
Yield
90%(alpha/beta=78/22)
MOLECULE ID
JCGG-COM0000347 (Reaction Tree)
Product Type
beta
Yield
90%(alpha/beta=78/22)
REACTION DETAIL
Reaction Time
3 hours
Reaction Temp
0 degree C
Solvent
CH2Cl2
Catalyst
Activator
Comment
CaSO4 was included in the solvent.
COMMENT
The PMID could not be found.
REFERENCE
Reference Id
REF-0000-000034
Source
Tetrahedron: Asymmetry 17 (2006) 2914-2918
Doi
10.1016/j.tetasy.2006.11.008

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)