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Glycan Syntheses |
JCGG ID |
JCGG-RAC0000604 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-000604
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Regist Date |
2012/06/21 16:14:41 | ||||
| REACTANT | |||||
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Mol |
56.6 micro mole | ||||
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Reactant Type |
AgOTf | ||||
Mol |
0.101 mmol | ||||
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Reactant Type |
gamma-collidine | ||||
Mol |
50.9 micro mole | ||||
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Mol |
50.9 micro mole | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
24% | ||||
| REACTION DETAIL | |||||
Reaction Time |
2 hours, 16 hours | ||||
Reaction Temp |
room temp, room temp | ||||
Solvent |
CH2Cl2, CH2Cl2 | ||||
Comment |
1) 8+AgOTf, gamma-collidine, MS 4A, 2) +7 | ||||
| MS 4A was included in the solvent. | |||||
| COMMENT | |||||
| There are two phases in this reaction. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000026 | ||||
Issn |
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Doi |
10.1021/ol051592z | ||||
PubMed ID |
16178547 | ||||
Journal Name |
Organic letters. (2005) 7 (20): 4415-8. | ||||
Article Title |
Di-tert-butylsilylene-directed alpha-selective synthesis of 4-methylumbelliferyl T-antigen. | ||||
Author |
Akihiro, Imamura; Hiromune, Ando; Hideharu, Ishida; Makoto, Kiso | ||||
Affiliation |
Department of Applied Bioorganic Chemistry, Gifu University, Gifu 501-1193, Japan. | ||||
Reference Id |
REF-0000-000027 | ||||
Source |
ORGANIC LETTERS, 2005, Vol. 7, No. 20, 4415-4418 | ||||
Doi |
10.1021/ol051592z | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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