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Glycan Syntheses |
JCGG ID |
JCGG-RAC0000601 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-000601
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Regist Date |
2012/06/21 16:14:32 | ||||
| REACTANT | |||||
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Mol |
64.2 micro mole | ||||
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Reactant Type |
Aryl alcohol | ||||
Mol |
0.192 mmol | ||||
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Mol |
83.4 micro mole | ||||
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Reactant Type |
40% in PhCH3 | ||||
Mol |
83.4 micro mole | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
56% | ||||
| REACTION DETAIL | |||||
Reaction Time |
36 hours | ||||
Reaction Temp |
reflux | ||||
Solvent |
anhydrous PhCH3 | ||||
Comment |
The combination of the reagents is equivalent to Mitsunobu condition. | ||||
| COMMENT | |||||
| There might be a typo in Supporting Info. (diethyl azocarboxylate) | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000026 | ||||
Issn |
|||||
Doi |
10.1021/ol051592z | ||||
PubMed ID |
16178547 | ||||
Journal Name |
Organic letters. (2005) 7 (20): 4415-8. | ||||
Article Title |
Di-tert-butylsilylene-directed alpha-selective synthesis of 4-methylumbelliferyl T-antigen. | ||||
Author |
Akihiro, Imamura; Hiromune, Ando; Hideharu, Ishida; Makoto, Kiso | ||||
Affiliation |
Department of Applied Bioorganic Chemistry, Gifu University, Gifu 501-1193, Japan. | ||||
Reference Id |
REF-0000-000027 | ||||
Source |
ORGANIC LETTERS, 2005, Vol. 7, No. 20, 4415-4418 | ||||
Doi |
10.1021/ol051592z | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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