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Glycan Syntheses |
JCGG ID |
JCGG-RAC0000596 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-000596
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Regist Date |
2012/06/21 16:14:16 | ||||
| REACTANT | |||||
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Mol |
3.0 equiv. | ||||
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Reactant Type |
azo compd | ||||
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Reactant Type |
phosphine | ||||
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Mol |
1.0 equiv. | ||||
| PRODUCT | |||||
MOLECULE ID |
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Product Type |
beta | ||||
Yield |
8% | ||||
MOLECULE ID |
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Product Type |
alpha | ||||
Yield |
74% | ||||
| REACTION DETAIL | |||||
Reaction Temp |
130 degree C | ||||
Solvent |
PhCH3 | ||||
Comment |
The amount of phosphine or azo compd could not be found. (considered to be 1.3 equiv. each) | ||||
| The reaction time could not be found. (considered to be about 10 hours) | |||||
| COMMENT | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000026 | ||||
Issn |
|||||
Doi |
10.1021/ol051592z | ||||
PubMed ID |
16178547 | ||||
Journal Name |
Organic letters. (2005) 7 (20): 4415-8. | ||||
Article Title |
Di-tert-butylsilylene-directed alpha-selective synthesis of 4-methylumbelliferyl T-antigen. | ||||
Author |
Akihiro, Imamura; Hiromune, Ando; Hideharu, Ishida; Makoto, Kiso | ||||
Affiliation |
Department of Applied Bioorganic Chemistry, Gifu University, Gifu 501-1193, Japan. | ||||
Reference Id |
REF-0000-000027 | ||||
Source |
ORGANIC LETTERS, 2005, Vol. 7, No. 20, 4415-4418 | ||||
Doi |
10.1021/ol051592z | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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