JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0000594
Submitter
The Noguchi Institute
Reaction ID
R-0000-000594
Regist Date
2012/06/21 16:14:09
REACTANT
MOLECULE ID
JCGG-COM0000608
Mol
3.0 equiv.
MOLECULE ID
JCGG-COM0000604 (Reaction Tree)
Mol
1.0 equiv.
MOLECULE ID
JCGG-COM0000585
Reactant Type
phosphine
MOLECULE ID
JCGG-COM0000613
Reactant Type
azo compd
PRODUCT
MOLECULE ID
JCGG-COM0000611 (Reaction Tree)
Product Type
alpha
Yield
8%
REACTION DETAIL
Reaction Temp
80 degree C
Solvent
THF
Comment
The reaction time could not be found. (considered to be about 10 hours)
The amount of phosphine or azo compd could not be found.
COMMENT
The details regarding this reaction are described in another paper in References.
REFERENCE
Reference Id
REF-0000-000026
Issn
Print
Doi
10.1021/ol051592z
PubMed ID
16178547
Journal Name
Organic letters. (2005) 7 (20): 4415-8.
Article Title
Di-tert-butylsilylene-directed alpha-selective synthesis of 4-methylumbelliferyl T-antigen.
Author
Akihiro, Imamura; Hiromune, Ando; Hideharu, Ishida; Makoto, Kiso
Affiliation
Department of Applied Bioorganic Chemistry, Gifu University, Gifu 501-1193, Japan.
Reference Id
REF-0000-000027
Source
ORGANIC LETTERS, 2005, Vol. 7, No. 20, 4415-4418
Doi
10.1021/ol051592z

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)