JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000589
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000589
Regist Date
 2012/06/21 16:13:55
REACTANT
MOLECULE ID
 JCGG-COM0000600 (Reaction Tree)
Mol
 1.84 mmol
MOLECULE ID
 JCGG-COM0000601 (Reaction Tree)
Skeleton
JCGG-STR031555
Mol
 1.53 mmol
MOLECULE ID
 JCGG-COM0000009
Reactant Type
 TMSOTf
Mol
 0.30 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0000602 (Reaction Tree)
Yield
 67%
REACTION DETAIL
Reaction Time
 60 minutes
Reaction Temp
 room temp
Solvent
 CH2Cl2
Catalyst
 TMSOTf
Comment
 AW-300 was included in the solvent.
COMMENT
REFERENCE
Reference Id
 REF-0000-000026
Issn
 Print
Doi
 10.1021/ol051592z
PubMed ID
 16178547
Journal Name
 Organic letters. (2005) 7 (20): 4415-8.
Article Title
 Di-tert-butylsilylene-directed alpha-selective synthesis of 4-methylumbelliferyl T-antigen.
Author
 Akihiro, Imamura; Hiromune, Ando; Hideharu, Ishida; Makoto, Kiso
Affiliation
 Department of Applied Bioorganic Chemistry, Gifu University, Gifu 501-1193, Japan.
Reference Id
 REF-0000-000027
Source
 ORGANIC LETTERS, 2005, Vol. 7, No. 20, 4415-4418
Doi
 10.1021/ol051592z
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)