JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000555
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000555
Regist Date
 2012/06/21 16:12:22
REACTANT
MOLECULE ID
 JCGG-COM0000567 (Reaction Tree)
Skeleton
JCGG-STR008276
Mol
 0.14 mmol
MOLECULE ID
 JCGG-COM0000568 (Reaction Tree)
Mol
 0.21 mmol
MOLECULE ID
 JCGG-COM0000129
Reactant Type
 NIS
Mol
 0.64 mmol
MOLECULE ID
 JCGG-COM0000009
Reactant Type
 TMSOTf
Mol
 42 micro mole
MOLECULE ID
 JCGG-COM0000491
Reactant Type
 AcOH
Volume
 8 mL
MOLECULE ID
 JCGG-COM0000531
Reactant Type
 H2O
Volume
 2 mL
PRODUCT
MOLECULE ID
 JCGG-COM0000569 (Reaction Tree)
Skeleton
JCGG-STR025272
Yield
 51%
REACTION DETAIL
Reaction Time
 6 hours, 2 hours, 48 hours
Reaction Temp
 room temp, 7 degree C, 45 degree C
Solvent
 PhH, PhH, AcOH/H2O = 8mL/2mL
Comment
 1) 4+5+MS 4A, 2) +NIS, TMSOTf, 3) +AcOH, H2O
MS 4A was included in the solvent.
COMMENT
The PMID could not be found.
There are three phases in this reaction.
REFERENCE
Reference Id
 REF-0000-000024
Source
 JOURNAL OF CARBOHYDRATE CHEMISTRY, Vol. 23, No. 4, pp. 201-215, 2004
Doi
 10.1081/CAR-200030039
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)