JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0000384
Submitter
The Noguchi Institute
Reaction ID
R-0000-000384
Regist Date
2012/06/21 15:47:28
REACTANT
MOLECULE ID
JCGG-COM0000377 (Reaction Tree)
Reactant Type
donor
Mol
1 equiv.
MOLECULE ID
JCGG-COM0000068 (Reaction Tree)
Skeleton
JCGG-STR032525
Reactant Type
Alcohol
Mol
1 equiv.
MOLECULE ID
JCGG-COM0000084
Reactant Type
activator
Mol
1 equiv.
MOLECULE ID
JCGG-COM0000035
Reactant Type
activator
Mol
0.05 equiv.
PRODUCT
MOLECULE ID
JCGG-COM0000387 (Reaction Tree)
Skeleton
JCGG-STR018936
Product Type
alpha
Yield
52%(alpha/beta=23/77)
MOLECULE ID
JCGG-COM0000388 (Reaction Tree)
Product Type
beta
Yield
52%(alpha/beta=23/77)
REACTION DETAIL
Reaction Time
overnight
Reaction Temp
room temp
Solvent
PhH
Catalyst
activator
Comment
MS 4A was included in the solvent.
COMMENT
The PMID could not be found.
The alpha/beta ratio was determined by the isolated yield.
REFERENCE
Reference Id
REF-0000-000014
Source
Bulletin of the Chemical Society of Japan, Vol. 67 (1994), No. 5 pp.1359-1366
Doi
10.1246/bcsj.67.1359

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)