|
Glycan Syntheses |
JCGG ID |
JCGG-RAC0000381 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-000381
|
||||
Regist Date |
2012/06/21 15:47:18 | ||||
| REACTANT | |||||
|
|
|
||||
Reactant Type |
donor | ||||
Mol |
1 equiv. | ||||
|
|
|
||||
Reactant Type |
Alcohol | ||||
Mol |
1 equiv. | ||||
|
|
|
||||
Reactant Type |
activator | ||||
Mol |
1 equiv. | ||||
|
|
|
||||
Reactant Type |
activator | ||||
Mol |
0.05 equiv. | ||||
| PRODUCT | |||||
MOLECULE ID |
|
|
|||
Product Type |
alpha | ||||
Yield |
69%(alpha/beta=27/73) | ||||
MOLECULE ID |
|
|
|||
Product Type |
beta | ||||
Yield |
69%(alpha/beta=27/73) | ||||
| REACTION DETAIL | |||||
Reaction Time |
overnight | ||||
Reaction Temp |
room temp | ||||
Solvent |
PhF | ||||
Catalyst |
activator | ||||
Comment |
MS 4A was included in the solvent. | ||||
| COMMENT | |||||
| The PMID could not be found. | |||||
| The alpha/beta ratio was determined by the measurement of 1H NMR. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000014 | ||||
Source |
Bulletin of the Chemical Society of Japan, Vol. 67 (1994), No. 5 pp.1359-1366 | ||||
Doi |
10.1246/bcsj.67.1359 | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
|