JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000377
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000377
Regist Date
 2012/06/21 15:47:05
REACTANT
MOLECULE ID
 JCGG-COM0000377 (Reaction Tree)
Reactant Type
 donor
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000031
Reactant Type
 Alcohol
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000084
Reactant Type
 activator
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000035
Reactant Type
 activator
Mol
 0.1 equiv.
PRODUCT
MOLECULE ID
 JCGG-COM0000378 (Reaction Tree)
Product Type
 alpha
Yield
 66%(alpha/beta=30/70)
MOLECULE ID
 JCGG-COM0000379 (Reaction Tree)
Product Type
 beta
Yield
 66%(alpha/beta=30/70)
REACTION DETAIL
Reaction Time
 overnight
Reaction Temp
 room temp
Solvent
 PhH
Catalyst
 activator
Comment
 MS 4A was included in the solvent.
COMMENT
The PMID could not be found.
The alpha/beta ratio was determined by the measurement of 1H NMR.
REFERENCE
Reference Id
 REF-0000-000014
Source
 Bulletin of the Chemical Society of Japan, Vol. 67 (1994), No. 5 pp.1359-1366
Doi
 10.1246/bcsj.67.1359
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)