JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000376
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000376
Regist Date
 2012/06/21 15:47:01
REACTANT
MOLECULE ID
 JCGG-COM0000386 (Reaction Tree)
Skeleton
JCGG-STR032397
Reactant Type
 Donor
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000068 (Reaction Tree)
Skeleton
JCGG-STR032525
Reactant Type
 Alcohol
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000084
Reactant Type
 activator
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000035
Reactant Type
 activator
Mol
 0.05 equiv.
PRODUCT
MOLECULE ID
 JCGG-COM0000384 (Reaction Tree)
Skeleton
JCGG-STR005837
Product Type
 alpha
Yield
 64%(alpha/beta=19/81)
MOLECULE ID
 JCGG-COM0000385 (Reaction Tree)
Skeleton
JCGG-STR003157
Product Type
 beta
Yield
 64%(alpha/beta=19/81)
REACTION DETAIL
Reaction Time
 overnight
Solvent
 PhH
Catalyst
 activator
Comment
 MS 4A was included in the solvent.
The reaction temperature could not be found. (considered to be room temp)
COMMENT
The PMID could not be found.
The alpha/beta ratio was determined by the measurement of 1H NMR.
REFERENCE
Reference Id
 REF-0000-000014
Source
 Bulletin of the Chemical Society of Japan, Vol. 67 (1994), No. 5 pp.1359-1366
Doi
 10.1246/bcsj.67.1359
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)