JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0000300
Submitter
The Noguchi Institute
Reaction ID
R-0000-000300
Regist Date
2012/06/21 15:17:45
REACTANT
MOLECULE ID
JCGG-COM0000170 (Reaction Tree)
Reactant Type
Fully benzylated sucrose-related oligosaccharide
Mol
0.14 mmol
MOLECULE ID
JCGG-COM0000334
Volume
0.8 mL
MOLECULE ID
JCGG-COM0000335
Volume
8 mL
PRODUCT
MOLECULE ID
JCGG-COM0000342 (Reaction Tree)
Product Type
Di- or trisaccharide unit
Yield
92%
MOLECULE ID
JCGG-COM0000336 (Reaction Tree)
Product Type
Monosaccharide unit
Yield
86%
REACTION DETAIL
Reaction Time
1 hour
Reaction Temp
room temp
Comment
75% aq H2SO4 was used.
COMMENT
The alpha/beta ratio for compound 12 = 19/31.
REFERENCE
Reference Id
REF-0000-000007
Issn
Print
Doi
10.1016/j.carres.2008.03.024
PubMed ID
18423585
Journal Name
Carbohydrate research. (2008) 343 (8): 1366-72.
Article Title
Preparation of partially benzylated mono-, di-, and trisaccharides by selective cleavage of the beta-fructofuranosidic linkage in fully benzylated sucrose and sucrose-related oligosaccharides under acidic conditions.
Author
Takashi, Yamanoi; Noriko, Misawa; Sho, Matsuda; Mikio, Watanabe
Affiliation
The Noguchi Institute, Tokyo, Japan. tyama@noguchi.or.jp
Reference Id
REF-0000-000008
Source
Carbohydrate Research 343 (2008) 1366‐1372
Doi
10.1016/j.carres.2008.03.024

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)