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Glycan Syntheses |
JCGG ID |
JCGG-RAC0000290 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-000290
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Regist Date |
2012/06/21 15:17:15 | ||||
| REACTANT | |||||
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Reactant Type |
1-Hydroxy sugar | ||||
Mol |
1 | ||||
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Reactant Type |
Activator | ||||
Mol |
0.10 | ||||
| PRODUCT | |||||
MOLECULE ID |
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Product Type |
alpha+alpha | ||||
Yield |
93%(alpha+alpha/alpha+beta/beta+beta=85/15/0) | ||||
MOLECULE ID |
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Product Type |
alpha+beta | ||||
Yield |
93%(alpha+alpha/alpha+beta/beta+beta=85/15/0) | ||||
| REACTION DETAIL | |||||
Reaction Time |
3.5 hours | ||||
Reaction Temp |
0 degree C | ||||
Solvent |
CH2Cl2 | ||||
Catalyst |
Activator | ||||
Comment |
anhydrous CaSO4 was included in the solvent. | ||||
| Scheme 2 | |||||
| COMMENT | |||||
| The PMID could not be found. | |||||
| The alpha/beta ratio was determined by NMR. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000012 | ||||
Source |
HETEROCYCLES, Vol. 77, No. 1, 2009, pp. 445 - 460 | ||||
Doi |
10.3987/COM-08-S(F)41 | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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