|
Glycan Syntheses |
JCGG ID |
JCGG-RAC0000281 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-000281
|
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Regist Date |
2012/06/21 15:16:53 | |||||||
| REACTANT | ||||||||
|
|
|
|||||||
Reactant Type |
1-Hydroxy sugar | |||||||
Mol |
1 | |||||||
|
|
|
|||||||
Reactant Type |
Activator | |||||||
Mol |
0.20 | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
|
|
|
|||||
Product Type |
alpha+alpha | |||||||
Yield |
84%(alpha+alpha/alpha+beta/beta+beta=65/29/6) | |||||||
MOLECULE ID |
|
|
||||||
Product Type |
alpha+beta | |||||||
Yield |
84%(alpha+alpha/alpha+beta/beta+beta=65/29/6) | |||||||
MOLECULE ID |
|
|
||||||
Product Type |
beta+beta | |||||||
Yield |
84%(alpha+alpha/alpha+beta/beta+beta=65/29/6) | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
1 day | |||||||
Reaction Temp |
room temp | |||||||
Solvent |
CH2Cl2 | |||||||
Catalyst |
Activator | |||||||
Comment |
anhydrous CaSO4 was included in the solvent. | |||||||
| Scheme 2 | ||||||||
| COMMENT | ||||||||
| The PMID could not be found. | ||||||||
| The alpha/beta ratio was determined by NMR. | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000012 | |||||||
Source |
HETEROCYCLES, Vol. 77, No. 1, 2009, pp. 445 - 460 | |||||||
Doi |
10.3987/COM-08-S(F)41 | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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