JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0000276
Submitter
The Noguchi Institute
Reaction ID
R-0000-000276
Regist Date
2012/06/21 15:16:40
REACTANT
MOLECULE ID
JCGG-COM0000046 (Reaction Tree)
Reactant Type
1-Hydroxy sugar
Mol
1
MOLECULE ID
JCGG-COM0000231
Reactant Type
Activator
Mol
0.05
PRODUCT
MOLECULE ID
JCGG-COM0000290 (Reaction Tree)
Skeleton
JCGG-STR001328
Yield
77%
MOLECULE ID
JCGG-COM0000294 (Reaction Tree)
Skeleton
JCGG-STR032525
Product Type
byproduct
Yield
19%
REACTION DETAIL
Reaction Time
10 minutes
Reaction Temp
reflux
Solvent
CH2Cl2
Catalyst
Activator
Comment
anhydrous CaSO4 was included in the solvent.
Scheme 2
COMMENT
The PMID could not be found.
The alpha/beta ratio was determined by NMR.
REFERENCE
Reference Id
REF-0000-000012
Source
HETEROCYCLES, Vol. 77, No. 1, 2009, pp. 445 - 460
Doi
10.3987/COM-08-S(F)41

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