JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000231
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000231
Regist Date
 2012/06/21 15:02:59
REACTANT
MOLECULE ID
 JCGG-COM0000048 (Reaction Tree)
Skeleton
JCGG-STR032525
Reactant Type
 Donor
Mol
 0.2 mmol
MOLECULE ID
 JCGG-COM0000060
Reactant Type
 Acceptor
Mol
 0.2 mmol
MOLECULE ID
 JCGG-COM0000084
Reactant Type
 activator
Mol
 0.2 mmol
MOLECULE ID
 JCGG-COM0000035
Reactant Type
 activator
Mol
 0.02 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0000061 (Reaction Tree)
Skeleton
JCGG-STR032525
Product Type
 alpha
Yield
 67%(alpha/beta=62/38)
MOLECULE ID
 JCGG-COM0000062 (Reaction Tree)
Skeleton
JCGG-STR031569
Product Type
 beta
Yield
 67%(alpha/beta=62/38)
REACTION DETAIL
Reaction Time
 overnight
Solvent
 benzene
Catalyst
 activator
Comment
 MS 4A was included in the solvent.
The reaction temperature could not be found. (considered to be room temp)
COMMENT
The PMID could not be found.
The alpha/beta ratio was determined by 1H NMR spectra.
REFERENCE
Reference Id
 REF-0000-000003
Source
 Bull. Chem. Soc. Jpn., 66, 2617-2622 (1993)
Doi
 10.1246/bcsj.66.2617
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)