JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000218
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000218
Regist Date
 2012/06/21 14:53:17
REACTANT
MOLECULE ID
 JCGG-COM0000262 (Reaction Tree)
Skeleton
JCGG-STR025316
Reactant Type
 Acceptor
Mol
 1
MOLECULE ID
 JCGG-COM0000236 (Reaction Tree)
Reactant Type
 Donor[1,3,4,6-tetra-O-benzoyl-D-fructofuranosyl acetate (alpha/beta=3/1)]
Mol
 1
MOLECULE ID
 JCGG-COM0000006
Reactant Type
 Activator
Mol
 0.05
PRODUCT
MOLECULE ID
 JCGG-COM0000263 (Reaction Tree)
Product Type
 alpha+alpha
Yield
 66%(alpha+alpha/alpha+beta/beta+alpha/beta/beta=14/5/67/14)
MOLECULE ID
 JCGG-COM0000264 (Reaction Tree)
Product Type
 alpha+beta
Yield
 66%(alpha+alpha/alpha+beta/beta+alpha/beta/beta=14/5/67/14)
MOLECULE ID
 JCGG-COM0000265 (Reaction Tree)
Product Type
 beta+alpha
Yield
 66%(alpha+alpha/alpha+beta/beta+alpha/beta/beta=14/5/67/14)
MOLECULE ID
 JCGG-COM0000266 (Reaction Tree)
Product Type
 beta+beta
Yield
 66%(alpha+alpha/alpha+beta/beta+alpha/beta/beta=14/5/67/14)
REACTION DETAIL
Reaction Time
 0.5 hour to overnight
Reaction Temp
 room temp
Solvent
 CH2Cl2
Catalyst
 Activator
Comment
 Anhydrous CaSO4 was included in the solvent.
COMMENT
The PMID could not be found.
CH2Cl2 was used as the solvent due to the poor solubility of aldopyranoses in PhCH3
REFERENCE
Reference Id
 REF-0000-000011
Source
 Tetrahedron Letters 48 (2007) 6458‐6462
Doi
 10.1016/j.tetlet.2007.07.092
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)