JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0000218
Submitter
The Noguchi Institute
Reaction ID
R-0000-000218
Regist Date
2012/06/21 14:53:17
REACTANT
MOLECULE ID
JCGG-COM0000262 (Reaction Tree)
Skeleton
JCGG-STR025316
Reactant Type
Acceptor
Mol
1
MOLECULE ID
JCGG-COM0000236 (Reaction Tree)
Reactant Type
Donor[1,3,4,6-tetra-O-benzoyl-D-fructofuranosyl acetate (alpha/beta=3/1)]
Mol
1
MOLECULE ID
JCGG-COM0000006
Reactant Type
Activator
Mol
0.05
PRODUCT
MOLECULE ID
JCGG-COM0000263 (Reaction Tree)
Product Type
alpha+alpha
Yield
66%(alpha+alpha/alpha+beta/beta+alpha/beta/beta=14/5/67/14)
MOLECULE ID
JCGG-COM0000264 (Reaction Tree)
Product Type
alpha+beta
Yield
66%(alpha+alpha/alpha+beta/beta+alpha/beta/beta=14/5/67/14)
MOLECULE ID
JCGG-COM0000265 (Reaction Tree)
Product Type
beta+alpha
Yield
66%(alpha+alpha/alpha+beta/beta+alpha/beta/beta=14/5/67/14)
MOLECULE ID
JCGG-COM0000266 (Reaction Tree)
Product Type
beta+beta
Yield
66%(alpha+alpha/alpha+beta/beta+alpha/beta/beta=14/5/67/14)
REACTION DETAIL
Reaction Time
0.5 hour to overnight
Reaction Temp
room temp
Solvent
CH2Cl2
Catalyst
Activator
Comment
Anhydrous CaSO4 was included in the solvent.
COMMENT
The PMID could not be found.
CH2Cl2 was used as the solvent due to the poor solubility of aldopyranoses in PhCH3
REFERENCE
Reference Id
REF-0000-000011
Source
Tetrahedron Letters 48 (2007) 6458‐6462
Doi
10.1016/j.tetlet.2007.07.092

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)