JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0000202
Submitter
The Noguchi Institute
Reaction ID
R-0000-000202
Regist Date
2012/06/21 14:52:31
REACTANT
MOLECULE ID
JCGG-COM0000236 (Reaction Tree)
Reactant Type
1,3,4,6-tetra-O-benzoyl-D-fructofuranosyl acetate (alpha/beta=3/1)
Mol
1
MOLECULE ID
JCGG-COM0000230
Reactant Type
Lewis acid(activator)
Mol
0.05
MOLECULE ID
JCGG-COM0000096
Mol
1
PRODUCT
MOLECULE ID
JCGG-COM0000237 (Reaction Tree)
Product Type
alpha
Yield
71%(alpha/beta=100/0)
REACTION DETAIL
Reaction Time
0.5 to 2 hours
Reaction Temp
room temp
Solvent
PhCH3
Catalyst
activator
Comment
Anhydrous CaSO4 was included in the solvent.
COMMENT
The PMID could not be found.
Only alpha was detected in the product.
REFERENCE
Reference Id
REF-0000-000011
Source
Tetrahedron Letters 48 (2007) 6458‐6462
Doi
10.1016/j.tetlet.2007.07.092

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)