Reaction:JCGG-RAC0000187

JCGG ID		JCGG-RAC0000187
Submitter		The Noguchi Institute
Reaction ID		R-0000-000187
Regist Date		2012/06/21 14:45:21
REACTANT
MOLECULE ID		JCGG-COM0000226 (Reaction Tree)
	Reactant Type	1,3,4,6-tetra-O-benzyl-D-frucofuranosyl acetate(alpha/beta=1/2)
	Mol	1
MOLECULE ID		JCGG-COM0000229
	Reactant Type	Lewis acid(activator)
	Mol	0.05
MOLECULE ID		JCGG-COM0000096
	Mol	1
PRODUCT
MOLECULE ID		JCGG-COM0000227 (Reaction Tree)
	Product Type	alpha
	Yield	95%(alpha/beta=75/25)
MOLECULE ID		JCGG-COM0000228 (Reaction Tree)
	Product Type	beta
	Yield	95%(alpha/beta=75/25)
REACTION DETAIL
Reaction Time		0.5 to 2 hours
Reaction Temp		0 degree C
Solvent		PhCH3
Catalyst		activator
		Cu(OTf)2
Comment		Anhydrous CaSO4 was included in the solvent.
COMMENT
The PMID could not be found.
REFERENCE
Reference Id		REF-0000-000011
	Source	Tetrahedron Letters 48 (2007) 6458‐6462
	Doi	10.1016/j.tetlet.2007.07.092