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Glycan Syntheses |
JCGG ID |
JCGG-RAC0000185 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-000185
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Regist Date |
2012/06/21 14:45:15 | ||||
| REACTANT | |||||
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Reactant Type |
1,3,4,6-tetra-O-benzyl-D-frucofuranosyl acetate(alpha/beta=1/2) | ||||
Mol |
1 | ||||
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Reactant Type |
Lewis acid(activator) | ||||
Mol |
0.05 | ||||
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Mol |
1 | ||||
| PRODUCT | |||||
MOLECULE ID |
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Product Type |
alpha | ||||
Yield |
89%(alpha/beta=65/35) | ||||
MOLECULE ID |
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Product Type |
beta | ||||
Yield |
89%(alpha/beta=65/35) | ||||
| REACTION DETAIL | |||||
Reaction Time |
0.5 to 2 hours | ||||
Reaction Temp |
0 degree C | ||||
Solvent |
PhH | ||||
Catalyst |
activator | ||||
| Sc(OTf)3 | |||||
Comment |
Anhydrous CaSO4 was included in the solvent. | ||||
| COMMENT | |||||
| The PMID could not be found. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000011 | ||||
Source |
Tetrahedron Letters 48 (2007) 6458‐6462 | ||||
Doi |
10.1016/j.tetlet.2007.07.092 | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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