JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0000164
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-000164
Regist Date
 2012/06/21 14:37:34
REACTANT
MOLECULE ID
 JCGG-COM0000201
Reactant Type
 aryl compound
Mol
 2 equiv.
MOLECULE ID
 JCGG-COM0000032
Reactant Type
 activator
Mol
 1 equiv.
MOLECULE ID
 JCGG-COM0000048 (Reaction Tree)
Skeleton
JCGG-STR032525
Mol
 1 equiv.
PRODUCT
MOLECULE ID
 JCGG-COM0000202 (Reaction Tree)
Product Type
 beta
Yield
 69%（alpha/beta=0/100）
REACTION DETAIL
Reaction Temp
 room temp
Solvent
 benzene
Catalyst
 activator
AgClO4
Reaction Type
 aryl glycosidation
Comment
 The reaction time could not be found. (considered to be short)
MS 4A was included in the solvent.
COMMENT
The PMID could not be found.
Only beta was detected in the product.
It is described that the yield% using 1 equiv amount of the aryl compound will change to 47%.
REFERENCE
Reference Id
 REF-0000-000010
Source
 Bulletin of the Chemical Society of Japan Vol. 67 (1994) , No. 5 pp.1488-1491
Doi
 10.1246/bcsj.67.1488
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)